| Company | Raised In | Commander | Rank |
| A | Clarksville | W.A. Forbes | Captain |
B | Montgomery County | M.G. Gholson | Captain |
C | Robertson County | Wash Lowe | Captain |
D | Stewart County | H.C. Buckner | Captain |
E | Stewart County | Clay Roberts | Captain |
F | Stewart County | W.E. Lowe | Captain |
G | Montgomery County | Isaac Brunson | Captain |
H | Clarksville | F.S. Beaumont | Captain |
I | Robertson County | W.P. Simmons | Captain |
K | Montgomery County | J.E. Lockert | Captain |
L | Montgomery County | E. Hewitt | Captain |
Clarksville lies at the heart of Montgomery County. Stewart County lies due west and Robertson County lies immediately to the east.
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Almost a thousand men formed the eleven companies that made up the Fourteenth Tennessee Infantry. The regiment used the Fairgrounds located in the vicinity of Dunbar Cave as its temporary headquarters. This was known as 'Camp Duncan.' The organization of the regiment was completed with the selection of the following field and staff officers:
| Oficer | Rank |
| W.A. Forbes | Colonel |
| M.O. Gholson | Lieutenant Colonel |
| N. Brandon | Major |
| W.W. Thompson | Adjutant |
| Dr. J.R. Johnson | Surgeon |
| Dr. John Martin | Assistant Surgeon |
| Major John Gorham | Quartermaster |
| Captain Frank Green | Commissary |
| R.J. Goosetree | Asst. Commissary |
| Dr. J.M. Pirtle | Chaplin |
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See Ordeal by Fire: A History of the Fourteenth Tennessee (Wallace Cross) 